The Environmental Case for Seawater Scrubbing
The romantic image of a luxury liner cruising blue seas amid blue skies and trailing a plume of smoke is too close to the truth for comfort. The emissions from shipping make an increasingly conspicuous contribution to air quality, health and environmental problems of Europe, and indeed, the world. Yet there are effective and safe technologies to dramatically reduce these emissions. There is a danger, however, that the widespread introduction of these technologies may be being discouraged, even blocked, by inappropriate and over-prescriptive legislation. Proposals based solely on reducing sulphur in fuel at refineries would achieve modest reductions in pollution at considerable environmental (and economic) cost, but concerns about the environmental performance of ship-board technologies for removing sulphur from exhaust gases are making legislators wary of a more innovative approach. This paper aims to address these concerns and to give a balanced view on seawater scrubbing for shipping. We present some environmental arguments for rapid and full support to the wide introduction of this technology. We believe that this is a win-win technology minimising environmental emissions at minimum cost to the industry.
Today’s mercantile fleet, unlike the sailing fleets of just 150 years ago, uses fossil fuel to propel itself. For the last 70 odd years, this fuel has been predominantly oil, and burning it, in engines or boilers, creates four general kinds of emissions:
· Sulphur Oxides, or SOx, come from burning the sulphur present to some degree in all oils, although there is less in the lighter fractions, such as car fuels. There are various geological cycles of sulphur, each with some impact on the environment. We explore what happens when mankind’s activities modify them, and how scrubbing can minimise this disturbance.
· Nitrogen Oxides, or NOx, is made when engines heat up the Nitrogen and Oxygen in air. Scrubbing does somewhat reduce these emissions (~10-15%), and it can compliment use of further NOx reduction technologies. Despite their environmental importance, they are not discussed further in this paper.
· Soot, or Particulate Matter (PM), consists of particles of many different materials, such as unburned fuel or incombustible elements in the fuel. Some of it are secondary particulates formed from SOx, NOx and other material in the atmosphere, which can condense in the plume away from the ship. The familiar “diesel smell” is largely due to the presence of PM. It comes in many different sizes, and there is some evidence which implicates the very small, or ultrafine, particles as the most harmful to us. Scrubbing dramatically reduces PM emissions.
· Carbon Dioxide, or CO2, is an inevitable product when we get energy from burning the carbon in fuel, and it is the main culprit implicated in global warming and climate change. Among the best ways of reducing CO2 is to use less energy. A shift of transport from air, rail or road will reduce CO2 emissions, as shipping is a particularly efficient form of transport. We also explore the energy efficiency of methods we use to reduce the other emissions.
Sulphur is an element we need to live and some 0.2% of our bodies are sulphur. We get the sulphur we need from our food, and plants get it from the soils in which they grow. Every year huge quantities of this sulphur are washed from the land to the sea. Some of it is replenished from the rocks of the earth, or from volcanoes or other sulphurous sources, (when it is called brimstone). Most is replenished by rain, which carries sulphur from the sea.
In its travels from sea to rain to land, and back again, we believe sulphur also plays a crucial climate control role, as follows:
· Micro organisms in the sea methylate the sulphur (that is they add methane groups (CH3) to it) and use this for their own biological processes. Other creatures may then eat them and capture this sulphur for their own uses. When they die, some of the sulphur turns to dimethyl sulphide (DMS), which is volatile, and some of it evaporates from the sea surface.
· Some of the sulphur also stays with the decaying organism, so in the past some went to make up the sulphur in the oil we now burn.
· The DMS in air provides a nucleation site for moisture to condense into clouds. Tiny particles of DMS help damp air turn into tiny droplets. The amount of DMS influences how quickly clouds are formed, and thus influences how much sunlight reaches the sea, and so how much rain falls. We now recognise this as a critical climate control mechanism.
· Much of the land upon which the DMS falls has plenty of various compounds of sulphur around already, so the ecology is not constrained by lack of sulphur. If you add more, nothing happens, except that more of it runs off back to the sea. A few ecologies are constrained by lack of sulphur, and have evolved to live with only that which falls in the rain. If more sulphur compounds land on these ecological communities, then some of the organisms in it will be able to grow bigger or faster. For most sulphur constrained ecologies, the addition of extra sulphur changes the balance of the ecology, often for the worse.
Sulphur is a naturally occurring element, obviously present all around us. The form in which it is present is a key factor determining whether it is beneficial, neutral or harmful.
Mankind, in its use of sulphur, influences these natural cycles, principally by releasing SOx into the atmosphere. SOx, unlike DMS, is typically only abundant in air during and close to volcanic eruptions. Thus our continuous and widespread generation of SOx presents environmental problems.
Most of the Sulphur Oxides (SOx) we release arise when we burn materials containing sulphur, such as most oils and coals. We also create smaller quantities of SOx, with their sulphurous smell, when we smelt sulphate ores in the extraction of metals, such as copper, zinc and lead, and it was perhaps this smelting that caused it to be one of the first air pollutants ever to be regulated.
Once released into air, SOx will combine with water droplets to form sulphuric acid, or with other particles in air to form sulphates. Although emitted as a gas, the gas can condense to form tiny crystals of SOx, which are (like natural DMS) nucleation sites for moisture (which then form Sulphuric Acid). SOx can travel a many thousands of kilometres from where it is emitted, but a “rule of thumb” is that half of total emissions will land within 720 kilometres of the source.
SOx combines readily with ammonia in the air to create ammonium sulphate, which causes a haze, reducing visibility and increasing the amount of incoming sunlight reflected back into the sky. As well as damaging “clear air”, it thus also influences the climate. When SOx is breathed it is irritating to nasal passages and the lungs, and is harmful to our health (as well as that of animals and plants).
When emitted SOx lands, it is, unlike DMS, largely as sulphuric acid, giving rise to the term Acid Rain. In many ecosystems, there is enough “buffering” in the water and the soil to neutralise the acid, and it behaves much as sulphur from natural sources. In many areas, this buffering capacity arises from the limestone or chalk geology of the soil. Older, alluvial soils tend also to have greater buffering capacity. After providing sulphur to the ecosystem (perhaps with a fertiliser effect) it runs off to the sea.
If the emitted SOx come down on buildings or statues, it rots them. Much of the loss of detail on historical monuments, particularly those of marble or limestone, is caused by reactions from acid rain dissolving the material.
Some ecosystems, particularly those associated with granite geology or thinner soils, do not have enough buffering capacity to neutralise the load of acid that lands. When this happens, the soil and freshwater environment turns more acid. As well as being corrosive, it is harmful to all life, with the harm growing as the concentration increases. Fish cannot survive in the water, and plants cannot survive in the soil. If the acid is concentrated by sudden releases, such as when snow melts, the effect can be lethal and quick. Many sensitive freshwater lakes are regularly treated with lime to neutralise the acidity and preserve the life of the lake.
Eventually, the SOx that lands on the soil is washed down the streams, with the acid gradually neutralised by other materials carried in the rivers to the sea.
If not neutralised before reaching the sea, the massive buffering capacity of seawater rapidly neutralises any remaining acidity.
In short, SOx in air are bad for us and on land they are often harmful. The sea is a natural sink for SOx, and is a place where sulphur is already enormously abundant. Indeed, the ultimate fate of all the sulphur runoff from land and air is the world’s oceans.
When SOx comes into contact with seawater there is a fast and efficient reaction between the SOx and Calcium Carbonate (CaCO3) in the seawater, to form Calcium Sulphate (gypsum) and CO2. The reaction neutralises the acidity of SOx, and consumes some of the buffering capacity of the seawater. The reaction is complete in a very short time, so the equipment to bring the exhaust gas with SOx and the seawater into contact can be compact and still achieve high reduction efficiencies (~95%).
The key environmental benefit of scrubbing is that it short circuits the whole SOx cycle, and returns the sulphur to the sea in the safest, quickest and least harmful way. This is the core environmental justification for scrubbing.
But further questions about scrubbing need answering:
We then discuss the further benefits arising from scrubbing, and safely disposing of, the PMs in the emissions.
Adding scrubbed sulphur to the sea does change its acidity very close to the source. However, the evidence available suggests that, in foreseeable practical uses, this change is barely detectable within a meter or two of any discharge. Certainly, any increase in the concentration of sulphur is miniscule (a few parts per million) compared to the sulphur already there. No known environmental harm is caused by such small changes and many rivers already have much larger increases in sulphur concentration.
We know that there are substances that are harmful at extraordinarily low concentrations, but in this case we are concerned with an increase in concentration of substances already present, not with new substances being added. Generally the local effect increases the proportion of sulphur in the sea from 928 parts per million (0.0928%) to perhaps 929 ppm. By way of comparison, we have increased the concentration of CO2 in our atmosphere from ~275 ppm to ~367 ppm, an increase of over 30%.
We do not yet know how far seawater can be diluted before it loses it scrubbing effectiveness, or the changes in acidity of sulphur content become large enough to cause harm. There is active research in this area. However, even enclosed harbours, with lock access, probably turn over enough seawater to handle likely discharges.
Shipping, like other large industrial plants, is able to handle and use the difficult heavy fuels that are unsuitable for other purposes, such as domestic heating, car or lorry transport, or air transport. To do so ships use complex fuel handling and processing machinery (quite unlike the filters in, for example, cars), but the extra cost is justified by the lower costs of the fuels they can then use.
These heavy fuels often concentrate the sulphur from the original crude oils. Although some heavy fuels can be made from the low sulphur crude oils, marine fuels reported to IMO average 2.7% sulphur. (This is 27,000 parts per million, whereas low sulphur car fuels are around 50 ppm).
So if shipping were to use low sulphur fuels, what would happen to all the high sulphur fuel oils they currently use? There appear to be five possible answers:
To decide whether land based FGD or sea water scrubbing deals most environmentally efficiently with the problem of sulphur in fossil fuel would require a full life cycle analysis of the two routes. It seems probable that removing sulphur in ships, which are floating in the neutralising material, would compare favourably with removal by land-based sources.
Fuel oil can be desulphurised. The process generally involves forming hydrogen (H2) and reacting this with the oil. The sulphur in the fuel reacts to form Hydrogen Sulphide, which is then further processed. The further processing may create Sulphuric Acid, a useful industrial chemical, or elemental sulphur, which is also of value in chemical industries. It may also be processed into gypsum for use in building materials.
The potential environmental attraction of this is that the sulphur recovered could replace sulphur that is otherwise mined as a feedstock to the chemical industry, and the gypsum could replace the gypsum that is mined.
There are disadvantages:
For many fuel uses, where no other means of removing SOx are available, the environmental benefits of desulphurisation can clearly outweigh these disadvantages, and continued investment and regulation to achieve lower sulphur levels is well directed. This is certainly the case for road transport fuels where even small quantities of sulphur reduce the effectiveness of catalysts used in exhaust gas treatment. When directed at desulphurisation of shipping fuels, the overall environmental benefit is less clear. This is particularly so when we consider the added CO2 burden from using energy intensive processes to remove the sulphur from fuel for shipping.
Once removed from fuels, the sulphur, mostly as sulphuric acid, is used in a rich variety of industrial and chemical processes. Indeed, sulphuric acid production is a key indicator of industrial activity. Some is also used in to manufacture fertiliser. However, almost all uses are dissipative. These uses neutralise it to form various sulphates. If soluble, these are eventually washed to the sea. If insoluble, they may be disposed of in landfill as well as carried to the sea as silt. Our efforts to reduce sulphur in fuels may still result in the sulphur making its way to our oceans.
New processes may be found that give other ways of using the sulphur, and if we reduced our dependence on fossil fuels, less would be released. But, at present, seawater scrubbing looks like a benign way to return the sulphur that comes from extraction of fossil oils to the ocean from which it once came.
All combustion processes, including ships engines, produce PMs, many of them very small and therefore carried a long way. Much depends upon the design and operation of the engine.
If the fuel used is low in sulphur, its PM emissions will generally be less. However, scrubbing reduces the emitted PMs much more than is currently possible using clean fuels and operating with well-tuned and well-designed engines.
It is only in the last decade or so that the scale of the health harm of PMs has become apparent, and the numbers are disturbingly large. In Denmark, which suffers particularly from PMs as well as from shipping emissions (it is nearly surrounded by shipping lanes), there are estimated to be some 5000 excess deaths per year, as well as many other morbidity effects. Other countries suffer similar effects. While the shipping contribution is not easily quantified, it is significant and the benefit of reductions in airborne PMs from shipping is substantial.
Such reductions are achieved as an additional (and arguable zero cost) environmental benefit of seawater scrubbing by shipping.
A key perceived disadvantage of scrubbing the PMs from exhaust is that the PMs (as well as the SOx) end up in the scrubbing water. If this water is not further treated, then its discharge would put this waste into the sea in a more concentrated form than it would be if it was first dispersed through air emissions. It does not add to the volumes of pollutants being put to the sea, just shortens the route by which it reaches the sea.
It is this discharge that is the focus of the main environmental objections to seawater scrubbing, and is quoted as a reason not to encourage (or even permit) seawater scrubbing.
Even without further treatment, the balance of environmental and health benefits will, in most ecosystems, outweigh any harm from these discharges. However, there are many ways of removing oily and solid wastes from water. Current shipping regulations have encouraged the installation and use of water cleaning technologies, and they are well understood by the industry. At sea, as well as in refineries, seawater that has been used for scrubbing can readily be treated before discharge, and the technical standards for such equipment will undoubtedly require that this is done. Sea-water scrubbing will require an on-going commitment to the complete safety of all discharges.
Seawater scrubbing of shipping exhausts is an environmentally benign way of reducing sulphurous and particulate emissions from ships, and provides a safe way of reducing the overall environmental sulphur burden our use of fossil fuels creates. There are substantial health and environmental benefits from the technology. The risks from this technology can be safely mitigated, resulting in a win-win opportunity that enables growth of the energy efficient shipping sector while substantially reducing its environmental burden.
It is for other papers to show that this is also minimises the economic burden on shipping, its passengers and its users.
Ayres, Robert U, with Ayres Leslie. Industrial ecology: towards closing the materials cycle. 1996. ISBN 1 85898 397 5
Bates, T.S., B.K. Lamb, A. Guenther, J. Dignon, and R.E. Stoiber (1992): Sulphur emissions to the atmosphere from natural sources. Journal of Atmospheric Chemistry, 14, 315-337.
Deffeyes, Kenneth S. Hubbert’s Peak: The Impending World Oil Shortage. Princeton University Press. ISBN 0691090866.
Ewart, W.D: Bunkers: A guide for the Ship Operator ISBN 0 905 045 37 8
Lovelock, James. Gaia: A New Look at Life on Earth. 1979. Reissued 1995. ISBN 0-19-286030-5
Raaschou-Nielsen; Palmgren, Finn; Solvang Jensen, Steen; Wåhlin; Berkowicz, Ruwin; Hertel, Ole; Vrang, Marie-Louise; Loft, Steffen H. Helbredseffekter af partikulær luftforurening i Danmark – et forsøg på kvantificering.
The Open University: Ocean Chemistry and Deep-Sea Sediments. ISBN 0 7506 4551 2
Clarke, R.B.: Marine Pollution, Fifth Edition. ISBN 0 19 879292 1
The responsibility for any errors in this paper is mine alone. But many have helped in the formation and explanation of the ideas, and reviewing the text, and I am most grateful to them all, including those who do not wish to be mentioned. In particular: Don Gregory, of BP Marine, who in pursuit of this technology has enabled the formation of what is now the Shipping Emissions Abatement and Trading group SEAaT (www.seaat.org) and shared so much of his thinking. Also (in no particular order) Andrew Trivett of DME; Professor John Murlis; Reidar Stockfleth, of Shell Marine Products; Richard Linger, of Cap Gemini Ernst & Young, and members of the SEAaT Steering Committee.
David Hirst (www.davidhirst.com) is a Management Consultant in Sustainability, and a core team member of SEAaT.
© David Hirst 2002, 2005
This work is distributed and released under the Copyleft conditions of the Design Science Licence, as published at http://www.gnu.org/licenses/dsl.html
This is version 1.02 of 15th October 2005, and has been updated to reflect the changed URL of the DSL licence. There has been no other change from 1.01 of 28th September 2002. The paper will be revised as new information becomes available, and comments and criticism are received. If you have comments or suggestions, please send them to email@example.com. If you plan to circulate or reuse the paper, please check for a later version at www.davidhirst.com/scrubb
 Some of the details of this cycle and their impact are still to be fully understood. Aspects of it remain topics of active scientific research.
 It is also currently by far the cheapest way, but the economic arguments are presented elsewhere.
 There is a small fuel consumption penalty of some 0.5%, but there are also heat recovery opportunities that can achieve consumption savings of 2% to 5% in most vessels.